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<article xsi:noNamespaceSchemaLocation="http://jats.nlm.nih.gov/publishing/1.1/xsd/JATS-journalpublishing1-mathml3.xsd" dtd-version="1.1" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"><front><journal-meta><journal-id journal-id-type="publisher-id">ME</journal-id><journal-title-group><journal-title>Modern Engineering</journal-title></journal-title-group><issn>2996-6973</issn><eissn>2996-6981</eissn><publisher><publisher-name>Art and Technology</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.61369/ME.2026040025</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title>PEI/PAA 层层自组装改性聚丙烯电池隔膜的制备及性能研究</title><url>https://artdesignp.com/journal/ME/3/4/10.61369/ME.2026040025</url><author>田雪凡,王占宇,王玮,吴江渝</author><pub-date pub-type="publication-year"><year>2026</year></pub-date><volume>3</volume><issue>4</issue><history><date date-type="pub"><published-time>2026-04-20</published-time></date></history><abstract>针对聚丙烯（PP）电池隔膜因润湿性差而影响充放电性能的问题，本文以聚乙烯亚胺（PEI）和聚丙烯酸（PAA）为聚电解质，对经等离子体预处理的PP隔膜进行层层自组装改性。采用扫描电镜、红外光谱及充放电循环测试对隔膜进行表征。结果显示：组装三层聚电解质后，隔膜对电解液的润湿能力大幅改善，接触角从原始PP的80.0&amp;plusmn;1.3&amp;deg;降至20.9&amp;plusmn;1.3&amp;deg; ；改性隔膜在1 C下循环500次后容量保持率为93.3%，远高于原始PP 的71.6%，证明改性有效提升了电池的循环稳定性。</abstract><keywords>PP 隔膜,润湿性,等离子体处理,循环稳定性</keywords></article-meta></front><body/><back><ref-list><ref id="B1" content-type="article"><label>1</label><element-citation publication-type="journal"><p>[1]Ju Y, Kim B, Youn B, et al. Towards dendrite-free lithium-ion batteries: A comprehensive review of functional separator technologies[J]. Journal of Energy Storage., 2025, 127: 116957.[2]Wang Y, Zhuang W, Bian H, et al. Lithium-ion battery separator using inorganic materials: A mini review[J]. Journal of Power Sources., 2025, 643: 237015.[3]Tong B, Li X. Towards separator safety of lithium-ion batteries: a review[J]. Materials Chemistry Frontiers, 2024, 8(2): 309-340.[4]Ding Y, Jiang Y, Zeng C, et al. Recent progress of advanced separators for Li-ion batteries[J]. Journal of Materials Science, 2024, 59(27): 12154-12176.[5]Liu Y, Li C Y, Li C, Lang Z Y, et al. Highly thermally stable, highly electrolyte-wettable hydroxyapatite/cellulose nanofiber hybrid separators for lithium-ion batteries[J].ACS Applied Energy Materials, 2023, 6: 2862-3871.[6]Yu Y, Cheng Z, Tian Z, et al. Roll-to-roll scalable manufacturing of nanoporous separators for high-safety lithium-ion batteries[J]. ACS Nano, 2026, 20(9).[7]Zhu X, Lu T, Guan X, et al. Atmospheric pressure plasma surface treatment to enhance interfacial insulation and water resistance of PP/SIR composite insulation[J].Applied Surface Science, 2026, 717: 164790.[8]Cao S, He X, Chen M, et al. A CF4 plasma functionalized polypropylene separator for dendrite-free lithium metal anodes[J]. Journal of Materials Chemistry A, 2023, 11(14): 7545-7555.[9]Su Z, Zhao G, Dou W. Preparing high chroma colored silica nanoparticles based on layer-by-layer self-assembled technique[J]. Journal of Sol-Gel Science and Technology,2022, 101(3):562-570.[10]Liang T, Wang Z, Nie H, et al. PES-C nanofiber separator grafting with polyethyleneimine for enhancing the ionic transport property in lithium-ion batteries[J]. Materials Letters, 2025, 394: 138663.[11]Guo X, Lu Y, Fu D, et al. Ultrahigh ionic conductivity and alkaline tolerance of poly(amidoxime)-based hydrogel for high performance piezoresistive sensor[J]. Chemical Engineering Journal, 2022.[12]Wang Z, Ouyang L, Li H, et al. Layer ‐by ‐layer assembly of strong thin films with high lithium-ion conductance for batteries and beyond[J]. Small, 2021, 17(32):2100954.[13]Wang Y, Chen H, Yu F, et al. Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries[J].Chinese Chemical Letters, 2024, 35(7).</p><pub-id pub-id-type="doi"/></element-citation></ref></ref-list></back></article>
